Angelina Jolie was in the wrong when she disclosed details of her relationship with Brad Pitt while they were filming “Mr. and Mrs. Smith,” Jennifer Aniston says, since she wasn’t even aware of her husband’s philandering then.

Aniston, who was married to Pitt but later divorced after his relationship with Jolie became public, sat down with Vogue for an interview for its December issue, during which she talks about the magazine’s 2007 profile of Jolie, who then talked about getting close with the then-still-married Pitt while shooting the action film in 2004.

"There was stuff printed there that was definitely from a time when I was unaware that it was happening," Aniston says. "I felt those details were a little inappropriate to discuss. That stuff about how she couldn’t wait to get to work every day? That was really uncool."

In an article in New York’s daily Metro today, Dorothy Robinson attempts to offer Aniston a bit of insight: "Oh, Jen. Jen, Jen, Jen. Don’t you realize that everything Angelina Jolie does is the epitome of cool? Even husband-stealing is considered ‘cool,’ when Angelina Jolie does it." Ouch.

Pitt and Aniston, who were married in July 2000 after being together for two years, announced their separation in January 2005. Before they were even divorced, Pitt was seen in public with Jolie. They now have six kids.

Aniston, who has two movies coming out in coming months — "Marley & Me" and "He’s Just Not That into You" — called actor Vince Vaughn, her co-star of the 2006 movie “The Break-Up,” her “defibrillator,” saying “he literally brought me back to life. My first gasp of air was a big laugh! It was great. I love him … He was lovely and fun and perfect for the time we had together. And I needed that. And it sort of ran its course."

As for her relationship with musician John Mayer, 31, with whom she split in August, she says: "Love just shows up and you go, ‘Oh, wow, this is going to be a hayride and a half.’"

When it comes to having children, though, she gets irritated.

"I’ve said it so many times: I’m going to have children. I just know it."

Aniston also talks about producing and directing films, her relationship with her mom and healing from her divorce with Pitt.

"We have exchanged a few very kind hellos and wishing you wells and sending you love and congratulations on your babies," she says of her ex-husband. "I have nothing but absolute admiration for him.”

You can read the entire interview and see photos here.

Click here to read From Cleopatra to Jennifer Aniston: Cougars We Love.